ETHYLENE
CHLOROHYDRIN
|
PRODUCT
IDENTIFICATION
|
CAS
NO. |
107-07-3
|
|
EINECS
NO. |
203-459-7 |
FORMULA |
ClCH2CH2OH |
MOL
WT. |
80.51 |
H.S.
CODE |
2905.50 |
TOXICITY
|
Oral
rat LD50: 71 mg/kg |
SYNONYMS |
2-Chloroethanol;
beta-Chloroethanol; |
Aethylenechlorhydrin
(German); 2-Chloorethanol (Dutch); 2- Chloraethanol
(German); 2-Chlorethanol (German); Delta-Chloroethanol;
Beta-Chloroethyl Alcohol; 2- Chloroethyl
Alcohol; Chloroethylowy Alkohol (Polish); 2- Cloroetanolo
(Italian); Ethyleen-chloorhydrine (Dutch); Ethylene
Chlorhydrin; Ethylene Chlorohydrin; Ethylene Glycol,
Chlorohydrin; Glicol Monocloridrina (Italian); Glycol
Chlorohydrin ; Glycolmonochloorhydrine (Dutch); Glycomonochlorhydrin;
Glycol Monochlorohydrin; Monochlorhydrine Du Glycol
(French); ет-Hydroxyethyl chloride; Chloroethanol; Ethylchlorohydrin;
Ethylene chlorhydrin; Glycol monochlorohydrin; 2-Chloro-1-ethanol;
2-Chloroethyl alcohol; 2-Hydroxyethyl chloride; beta-Chloroethyl
alcohol; |
SMILES
|
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
clear,
poisonous liquid |
MELTING
POINT |
-89
C |
BOILING
POINT |
130
C |
SPECIFIC
GRAVITY |
1.021 |
SOLUBILITY
IN WATER |
miscible |
pH |
|
VAPOR
DENSITY |
2.78 |
AUTOIGNITION
|
425
C |
NFPA
RATINGS |
Health:
3; Flammability: 2; Reactivity: 0 |
REFRACTIVE
INDEX
|
1.4410 |
FLASH
POINT |
55
C
|
STABILITY |
Stable
under ordinary conditions |
APPLICATIONS
|
Ethylene
Chlorohydrin is used as a solvent for celluloses resins
and waxes and as a cleaning agent. It is also an extraction
solvent for the separation of butadiene from hydrocarbon
mixtures, for the dewaxing and removing cycloalkanes
from mineral oil, for pure lignin and for the refining
of rosin. It is used as a hydroxyethylating agent in
organic synthesis such as ethylene oxide, ethylene glycol,
amines, carbitols, indigo, malonic acid and novocaine.
Its end aplications include dye intermediates, pharmaceuticals,
agrochemicals, pesticides, plasticizers and others.
|
SALES
SPECIFICATION |
APPEARANCE
|
almost
colorless liquid
|
ASSAY
(G.C.)
|
99.0%
min
|
ACID
NUMBER
|
0.2
max (mg KOH/g)
|
WATER
|
0.1%
max
|
TRANSPORTATION |
PACKING |
200kgs
in drum |
HAZARD
CLASS |
6.1
(Packing Group: I) |
UN
NO. |
1135 |
OTHER
INFORMATION |
European Hazard
Symbols: T+, Risk Phrases: 26/27/28, Safety Phrases:
7/9-9-16-28-28A-33-37-45 |
GENERAL
DESCRIPTION OF HALOHYDRIN
|
Halohydrin is an alkane
compound in which one carbon has a halogen substituent and
the other carbon has a hydroxyl substituent. Halohydrin undergoes internal SN2 reaction to an ether
(epoxide). Certain halohydrin is used as a solvent and
as a cleaning agent. 3-Bromo-1-Propanol, trimethylene
bromohydrin,
is used as an intermediate for the synthesis of target
molecules.
Members
of halohydrin compound
Product
|
CAS
RN
|
2-Chloro-1-propanol
| 78-89-7 |
Glycerol alpha-monochlorohydrin |
96-24-2 |
2,3-Dibromo-1-Propanol |
96-13-9 |
1,3-Dibromo-2-propanol
|
96-21-9 |
1,3-Dichloro-2-propanol
|
96-23-1 |
Ethylene chlorohydrin
|
107-07-3 |
Sodium
3-chloro-2-hydroxypropylsulfonate |
126-83-0 |
1-Chloro-2-propanol
|
127-00-4 |
Ethylene fluorohydrin |
371-62-0 |
Propylene fluorohydrin |
430-50-2 |
3-Fluoro-1,2-propanediol
|
453-16-7
|
2-Chloropropane-1,3-diol
|
497-04-1 |
Chlorocyanohydrin
|
513-96-2 |
1,3-Diiodo-2-propanol
|
534-08-7 |
Ethylene bromohydrin
|
540-51-2 |
Glyceryl iodide
|
554-10-9 |
2,3-Dichloro-1-propanol
|
616-23-9 |
Ethylene iodohydrin |
624-76-0 |
3-Chloro-1-propanol
|
627-30-5 |
3-Bromo-1-propanol
|
627-18-9
|
4-Chloro-1-butanol
|
928-51-8
|
Butylene chlorohydrin
| 1320-66-7 |
1-Propanol,
3-bromo-2,2-bis(bromoethyl)- | 1522-92-5 |
11-Bromo-1-undecanol
|
1611-56-9
|
2-Chloro-1-phenylethanol
| 1674-30-2 |
Hexamethylene Chlorohydrin |
2009-83-8 |
Loprodiol | 2209-86-1 |
Pentaerythritol
dibromide | 3296-90-0 |
6-Bromo-1-hexanol
|
4286-55-9
|
2-Propanol,
1-chloro-3-(2-propenyloxy)- |
4638-03-3 |
alpha-Bromohydrin
|
4704-77-2 |
5-Chloropentanol
| 5259-98-3 |
2-Propanol,
1-butoxy-3-chloro- | 16224-33-2 |
(S)-(+)-2-chloropropan-1-ol
|
19210-21-0
|
1-bromo-2-propanol |
19686-73-8 |
alpha-Chlorohydrin-1-phosphate
| 26807-13-6 |
4-Bromo-1-butanol
|
33036-62-3
|
8-Bromo-1-octanol
|
50816-19-8
|
10-Bromo-1-decanol
|
53463-68-6
|
9-Bromo-1-nonanol
|
55362-80-6
|
(R)-(-)-3-Chloro-1,2-propanediol
|
57090-45-6
|
(S)-(+)-3-Chloro-1,2-propanediol
|
60827-45-4
|
|
|