ETHYLENE CHLOROHYDRIN

PRODUCT IDENTIFICATION

CAS NO.

107-07-3

ETHYLENE CHLOROHYDRIN

EINECS NO. 203-459-7
FORMULA ClCH2CH2OH
MOL WT. 80.51
H.S. CODE 2905.50

TOXICITY

Oral rat LD50: 71 mg/kg
SYNONYMS 2-Chloroethanol; beta-Chloroethanol;
Aethylenechlorhydrin (German); 2-Chloorethanol (Dutch); 2- Chloraethanol (German); 2-Chlorethanol (German); Delta-Chloroethanol; Beta-Chloroethyl Alcohol; 2- Chloroethyl Alcohol; Chloroethylowy Alkohol (Polish); 2- Cloroetanolo (Italian); Ethyleen-chloorhydrine (Dutch); Ethylene Chlorhydrin; Ethylene Chlorohydrin; Ethylene Glycol, Chlorohydrin; Glicol Monocloridrina (Italian); Glycol Chlorohydrin ; Glycolmonochloorhydrine (Dutch); Glycomonochlorhydrin; Glycol Monochlorohydrin; Monochlorhydrine Du Glycol (French); ет-Hydroxyethyl chloride; Chloroethanol; Ethylchlorohydrin; Ethylene chlorhydrin; Glycol monochlorohydrin; 2-Chloro-1-ethanol; 2-Chloroethyl alcohol; 2-Hydroxyethyl chloride; beta-Chloroethyl alcohol;

SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE clear, poisonous liquid
MELTING POINT -89 C
BOILING POINT 130 C
SPECIFIC GRAVITY 1.021
SOLUBILITY IN WATER miscible
pH

 

VAPOR DENSITY 2.78
AUTOIGNITION 425 C
NFPA RATINGS Health: 3; Flammability: 2; Reactivity: 0

REFRACTIVE INDEX

1.4410
FLASH POINT

55 C

STABILITY Stable under ordinary conditions

APPLICATIONS

Ethylene Chlorohydrin is used as a solvent for celluloses resins and waxes and as a cleaning agent. It is also an extraction solvent for the separation of butadiene from hydrocarbon mixtures, for the dewaxing and removing cycloalkanes from mineral oil, for pure lignin and for the refining of rosin. It is used as a hydroxyethylating agent in organic synthesis such as ethylene oxide, ethylene glycol, amines, carbitols, indigo, malonic acid and novocaine. Its end aplications include dye intermediates, pharmaceuticals, agrochemicals, pesticides, plasticizers and others.
SALES SPECIFICATION

APPEARANCE

almost colorless liquid

ASSAY (G.C.)

99.0% min

ACID NUMBER

0.2 max (mg KOH/g)

WATER

0.1% max

TRANSPORTATION
PACKING 200kgs in drum
HAZARD CLASS 6.1 (Packing Group: I)
UN NO. 1135
OTHER INFORMATION
European Hazard Symbols: T+, Risk Phrases: 26/27/28, Safety Phrases: 7/9-9-16-28-28A-33-37-45

GENERAL DESCRIPTION OF HALOHYDRIN

Halohydrin is an alkane compound in which one carbon has a halogen substituent and the other carbon has a hydroxyl substituent. Halohydrin undergoes internal SN2 reaction to an ether (epoxide). Certain halohydrin is used as a solvent and as a cleaning agent. 3-Bromo-1-Propanol, trimethylene bromohydrin, is used as an intermediate for the synthesis of target molecules.

Members of halohydrin compound

Product

CAS RN

2-Chloro-1-propanol 78-89-7
Glycerol alpha-monochlorohydrin 96-24-2
2,3-Dibromo-1-Propanol 96-13-9
1,3-Dibromo-2-propanol 96-21-9
1,3-Dichloro-2-propanol 96-23-1
Ethylene chlorohydrin 107-07-3
Sodium 3-chloro-2-hydroxypropylsulfonate 126-83-0
1-Chloro-2-propanol 127-00-4
Ethylene fluorohydrin 371-62-0
Propylene fluorohydrin 430-50-2

3-Fluoro-1,2-propanediol

453-16-7

2-Chloropropane-1,3-diol 497-04-1
Chlorocyanohydrin 513-96-2
1,3-Diiodo-2-propanol 534-08-7
Ethylene bromohydrin 540-51-2
Glyceryl iodide 554-10-9
2,3-Dichloro-1-propanol 616-23-9
Ethylene iodohydrin 624-76-0
3-Chloro-1-propanol 627-30-5

3-Bromo-1-propanol

627-18-9

4-Chloro-1-butanol

928-51-8

Butylene chlorohydrin 1320-66-7
1-Propanol, 3-bromo-2,2-bis(bromoethyl)- 1522-92-5

11-Bromo-1-undecanol

1611-56-9

2-Chloro-1-phenylethanol 1674-30-2
Hexamethylene Chlorohydrin 2009-83-8
Loprodiol2209-86-1
Pentaerythritol dibromide 3296-90-0

6-Bromo-1-hexanol

4286-55-9

2-Propanol, 1-chloro-3-(2-propenyloxy)- 4638-03-3
alpha-Bromohydrin 4704-77-2
5-Chloropentanol 5259-98-3
2-Propanol, 1-butoxy-3-chloro- 16224-33-2

(S)-(+)-2-chloropropan-1-ol

19210-21-0

1-bromo-2-propanol 19686-73-8
alpha-Chlorohydrin-1-phosphate 26807-13-6

4-Bromo-1-butanol

33036-62-3

8-Bromo-1-octanol

50816-19-8

10-Bromo-1-decanol

53463-68-6

9-Bromo-1-nonanol

55362-80-6

(R)-(-)-3-Chloro-1,2-propanediol

57090-45-6

(S)-(+)-3-Chloro-1,2-propanediol

60827-45-4